Hi and welcome to the forum. I'm going to wade in and guess the can of worms that is colour management.
You are taking a screenshot of the web from a browser (If I follow correctly), a few browsers have colour managed spaces, a lot don't, you are then taking that into a (I guess), badly colour managed Photoshop.
If you look at all the values none of them match but the RGB and HSB. The most important question should be, what colour do I want? Only look at that, if you know the values input those, if not read up on a large subject.
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